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Organolithium reagent
Organolithium reagent An organolithium reagent is an organometallic compound with a direct ... the carbon atom, effectively creating a carbanion, organolithium compounds are extremely powerful bases and ...
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Gilman reagent
Gilman reagent A Gilman reagent is a lithium and copper (diorganocopper) reagent compound, , where ... were discovered by Henry Gilman. See also Organolithium reagent Grignard reagent External links National Pollutant ...
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Grignard reagent
Grignard reagent A Grignard Reagent is an alkyl- or aryl- magnesium halide. This reagent is important in the synthesis of carbon ... for his discovery of Grignard reagents. Grignard reagent formation Grignard reagents are formed by reacting ... is present, which would otherwise cause the reagent to rapidly decompose. Thus, most Grignard ...
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Category:Reagents for organic chemistry
Category:Reagents for organic chemistry Main article: reagent This category was created to provide a ... Adkins catalyst Aluminium chloride Azobisisobutylonitrile B Burgess reagent C CBS catalyst Carbonyldiimidazole Chromic acid Copper ... cont. Dichlorocarbene Diethyl azodicarboxylate F Fenton's reagent Fremy's salt G Gilman reagent Glycol cleavage Grignard reagent L Lawesson's reagent Lithium aluminium ...
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Carbene
... is generation of carbene. A well-known reagent employed for alkene-to-cyclopropane reactions is Simmons-Smith reagent. This reagents is a system of copper, zinc, and iodine, where the active reagent is believed to be iodomethylzinc iodide. Reagent is complexed by hydroxy groups such that ... or HX from CHX 3 moiety, employing organolithium reagents (or another strong base). It ...
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Category:Lithium compounds
... this section of this category. G Gilman reagent L Lithium acetate Lithium aluminium hydride Lithium ... Lithium salt Lithium sulphide Lithium tantalate O Organolithium compound Organolithium reagent
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Category:Organometallic compounds
... this category. D DIBAH Dimethylmercury G Gilman reagent G cont. Grignard reagent M Mercury fulminate Methylcyclopentadienyl Manganese Tricarbonyl Methylmercury O Organolithium reagent T Tetra-ethyl lead Trimethylaluminium
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N-Butyllithium
... compound n-butyllithium is the most prominent organolithium reagent. It has wide use as a polymer ... production and consumption of butyllithium and other organolithium compounds is estimated at 1800 metric tonnes ...
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Lithium diisopropylamide
... generation of carbanions. It is a convenient reagent for use in organic chemistry because it ... solution. LDA is one of the few organolithium compounds which is has a rigorously characterized ... often dissociates to engage in reactivity. Other organolithium compounds are generally considered to exist in ...
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Zinc chloride
... ZnCl 2 (known together as the "Lucas reagent") at 130 °C is effective for the ... is usually prepared by transmetallation from an organolithium or a Grignard reagent, for example: Zinc enolates, prepared from alkali ...
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